Publications

Watson, L. A.; Leahy, D.; Evans, P. A.; Caulton, K. G.  Characterization and Evaluation of the Pre-Catalyst Components Employed in the Stereospecific Rhodium-Catalyzed Allylic Substitution Reaction.  Submitted for publication.

Watson, L. A.; Walstrom, A. N.; Pink, M.; Caulton, K. G.  Reactivity of the 14-Valence Electron, Spin Triplet [(tBu2PCH2SiMe2)2N]RuCl, (PNPtBu)RuCl. Submitted for publication.

Gerber, L. C. H.; Watson, L. A.; Parkin, S.; Wang, W.; Foxman, B. M.; Ozerov, O. V. Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand. Organometallics, 2007, 26, 4866.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. Operationally Unsaturated Pincer/Rhenium Complexes form Metal Carbenes from Cycloalkenes and Metal Carbynes from Alkanes. J. Am. Chem. Soc., 2007, 129, 6003.

Basuli, F.; Bailey, B. C.; Watson, L. A.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality. Organometallics, 2005, 24, 1886.

Çelenligil-Çetin, R.; Watson, L. A.; Guo, C.; Foxman, B.; Ozerov, O. Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center. Organometallics, 2005, 24, 186.

Watson, L. A.; Pink, M.; Caulton, K. G.  The Fate of Nitric Oxide in Its Reaction with the 14-valence-electron Planar Species [(tBu2PCH2SiMe2)2N]RuCl. J. Mol. Cat. A: Chemical, 2004, 224, 51.

Ozerov, O.; Watson, L. A.; Pink, M.; Baik, M-H.; Caulton, K. G. Terminal Acetylenes React to Increase Unsaturation in [(tBu2PCH2SiMe2)2N]Re(H)4. Organometallics, 2004, 23, 4934.

Walstrom, A. N.; Watson, L. A.; Pink, M.; Caulton, K. G.  Facile Insertion of Terminal Acetylenes in the RuII-NR2 Bond of a 14-valence Electron Complex. Organometallics, 2004, 23, 4814.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. Transformation of acyclic alkenes to hydrido carbynes by (PNPR)Re complexes. J. Am. Chem. Soc., 2004, 126, 6363.

Ozerov, O.; Pink, M.; Watson, L. A.; Caulton, K. G. Aromatic vs. Aliphatic C-H Cleavage of Alkyl-Substituted Pyridines By (PNPiPr)Re Compounds. J. Am. Chem. Soc., 2004, 126, 2105.

Watson, L. A.; Franzman, B.; Bollinger, J. C.; Caulton, K. G. p-Donor Olefin Substituents alter Olefin Binding to CpFe(CO)2+.  New J. Chem., 2003, 27, 1769.

Basuli, F.; Watson, L. A.; Huffman, J. C.; Mindiola, D. J. Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene. J. Chem. Soc., Dalton Trans., 2003, 22, 4228.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. A p-Basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand. J. Am. Chem. Soc., 2003, 125, 9604.

Ho, V. M.; Watson, L. A.; Caulton, K. G. Double C(sp3) Dehydrogenation as a Route to Coordinated Arduengo Carbenes: Experiment and Computation on Comparative π-Acidity.  New J. Chem., 2003, 27, 1446.

Watson, L. A.; Ozerov, O.; Pink, M.; Caulton, K. G. Four-coordinate, Planar Ru(II).  A Triplet State as a Response to a 14 Valence Electron Configuration.  J. Am. Chem. Soc., 2003, 125, 8426.

Ozerov, O. V.; Huffman, J. C.; Watson, L. A.; Caulton, K. G. Conversion of Ethylene to Hydride and Ethylidyne by Amido Rhenium Polyhydride. Organometallics, 2003, 22, 2539.

Watson, L. A.; Coalter, J. N.; Ozerov, O.; Pink, M.; Huffman, J. C.; Caulton, K. G. Amido/Phosphine Pincer Hydrides of Ruthenium. New J. Chem., 2003, 27, 263.

Ozerov, O. V.; Gerard, H. F.; Watson, L. A.; Huffman, J. C.; Caulton, K. G. Double Silyl Migration Converting ORe[NSiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] Substructures.  Inorg. Chem., 2002, 41, 5615.

Watson, L. A.; Eisenstein, O. Entropy Explained: the origin of some simple trends.  J. Chem. Ed., 2002, 79, 1269.

Watson, L. A.; Caulton, K. G.  Assessing Isomeric Structures of Pincer-ligated Ruthenium and Osmium Polyhydrides using Density Functional Calculations.  Molecular Physics, 2002, 100, 385.

Watson, L. A.; Yandulov, D. V.; Caulton, K. G. C-Do (Do=π-donor, F) Cleavage in H2C:CH(Do) by (Cp2ZrHCl)n: Mechanism, Agostic Fluorines, and a Carbene of Zr(IV).  J. Am. Chem. Soc., 2001, 123, 603.

   

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